Table 3.
Metal Ions | CGCS_CPLH+ | ||||||
---|---|---|---|---|---|---|---|
ΔH°, J mol−1 |
ΔS°, kJ mol−1 K−1 |
ΔG°, kJ·mol−1 | |||||
293 | 298 | 303 | 308 | 313 | |||
Cu2+ | 74.79 | 0.318 | −18.67 | −19.93 | −21.34 | −23.31 | −24.97 |
Zn2+ | 59.74 | 0.261 | −17.02 | −18.16 | −19.40 | −20.64 | −22.34 |
Ni2+ | 25.22 | 0.047 | −9.42 | −10.17 | −10.78 | −11.32 | −11.81 |
Fe3+ | 86.42 | 0.356 | −18.08 | −19.42 | −21.27 | −23.02 | −25.21 |
Cr3+ | 45.29 | 0.185 | −9.02 | −10.34 | −11.03 | −12.07 | −12.80 |
CGCS | |||||||
ΔH°, J·mol−1 |
ΔS°, kJ mol−1 K−1 |
ΔG°, kJ·mol−1 | |||||
293 | 298 | 303 | 308 | 313 | |||
Cu2+ | 34.42 | 0.171 | −15.61 | −16.65 | −17.37 | −18.33 | −19.04 |
Zn2+ | 83.76 | 0.329 | −12.88 | −14.44 | −16.03 | −17.82 | −19.45 |
Ni2+ | 46.86 | 0.176 | −4.89 | −5.74 | −6.78 | −7.67 | −8.34 |
Fe3+ | 37.31 | 0.476 | −14.24 | −15.19 | −16.10 | −16.90 | −17.80 |
Cr3+ | 104.93 | 0.188 | −7.83 | −9.09 | −10.03 | −10.91 | −11.61 |
CPLH+ | |||||||
ΔH°, J·mol−1 |
ΔS°, kJ mol−1 K−1 |
ΔG°, kJ·mol−1 | |||||
293 | 298 | 303 | 308 | 313 | |||
Cu2+ | 14.38 | 0.090 | −12.12 | −12.55 | −13.04 | −13.46 | −13.92 |
Zn2+ | 26.17 | 0.114 | −7.16 | −7.83 | −8.37 | −8.96 | −9.45 |
Ni2+ | 19.61 | 0.077 | −3.02 | −3.45 | −3.95 | −4.26 | −4.55 |
Fe3+ | 17.03 | 0.093 | −10.43 | −10.95 | −11.43 | −11.88 | −12.30 |
Cr3+ | 60.08 | 0.223 | −5.21 | −6.71 | −7.83 | −8.75 | −9.76 |