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. 2020 Jun 8;25(11):2664. doi: 10.3390/molecules25112664

Table 3.

Thermodynamic parameters for the sorption of Cu2+, Zn2+, Ni2+, Fe3+, and Cr3+ ions onto investigated sorbents.

Metal Ions CGCS_CPLH+
ΔH°,
J mol−1
ΔS°,
kJ mol−1 K−1
ΔG°, kJ·mol−1
293 298 303 308 313
Cu2+ 74.79 0.318 −18.67 −19.93 −21.34 −23.31 −24.97
Zn2+ 59.74 0.261 −17.02 −18.16 −19.40 −20.64 −22.34
Ni2+ 25.22 0.047 −9.42 −10.17 −10.78 −11.32 −11.81
Fe3+ 86.42 0.356 −18.08 −19.42 −21.27 −23.02 −25.21
Cr3+ 45.29 0.185 −9.02 −10.34 −11.03 −12.07 −12.80
CGCS
ΔH°,
J·mol−1
ΔS°,
kJ mol−1 K−1
ΔG°, kJ·mol−1
293 298 303 308 313
Cu2+ 34.42 0.171 −15.61 −16.65 −17.37 −18.33 −19.04
Zn2+ 83.76 0.329 −12.88 −14.44 −16.03 −17.82 −19.45
Ni2+ 46.86 0.176 −4.89 −5.74 −6.78 −7.67 −8.34
Fe3+ 37.31 0.476 −14.24 −15.19 −16.10 −16.90 −17.80
Cr3+ 104.93 0.188 −7.83 −9.09 −10.03 −10.91 −11.61
CPLH+
ΔH°,
J·mol−1
ΔS°,
kJ mol−1 K−1
ΔG°, kJ·mol−1
293 298 303 308 313
Cu2+ 14.38 0.090 −12.12 −12.55 −13.04 −13.46 −13.92
Zn2+ 26.17 0.114 −7.16 −7.83 −8.37 −8.96 −9.45
Ni2+ 19.61 0.077 −3.02 −3.45 −3.95 −4.26 −4.55
Fe3+ 17.03 0.093 −10.43 −10.95 −11.43 −11.88 −12.30
Cr3+ 60.08 0.223 −5.21 −6.71 −7.83 −8.75 −9.76