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. 2020 May 28;142(25):11279–11294. doi: 10.1021/jacs.0c04742

Scheme 1. Current State of the Art: Triarylsilanolate Catalysts That Tolerate Diverse Functionality and Complex Settings but Fail with Simple Unhindered Alcohols.

Scheme 1

Complex 2 was released in situ from the corresponding ate complex chosen as precatalyst, cf. ref (17c).