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. 2020 May 28;142(25):11279–11294. doi: 10.1021/jacs.0c04742

Table 1. Relevant 95Mo, 29Si, and 13C NMR Shifts ([D8]-Toluene, ppm) of Molybdenum p-Methoxybenzylidyne Complexes Bearing Different Silanolate Ligands.

complex 95Mo (δ) 29Si (δ) 13C (δ)
1d 358 +10.2 303.3
2a 397 –8.0 300.5
1c 414 –9.1 309.3
1a 419 –9.9 310.4
1b 434 –9.8 311.4