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. 2020 Jul 2;15(7):e0235416. doi: 10.1371/journal.pone.0235416

Table 1. Compounds identified from Plectranthus amboinicus leaf volatiles harvested at 8.00 AM using HS-SPME-GC-MS analysis.

No RTa (min) Compounds RIb Relative contentc (%)
1 8.304 β-Thujene 924 0.432 ± 0.048
2 10.081 1-Octen-3-ol 983 1.140 ± 0.054
3 10.279 β-Myrcene 990 1.372 ± 0.147
4 10.653 α-Phellandrene 1002 0.458 ± 0.030
5 11.043 α-Terpinene 1015 2.508 ± 0.212
6 11.434 ρ-Cymene 1027 8.208 ± 0.445
7 12.069 β-Ocimene 1048 0.149 ± 0.015
8 12.512 γ-Terpinene 1063 10.475 ± 0.465
9 13.229 Terpinolene 1086 0.161 ± 0.003
10 13.683 Linalool 1101 0.163 ± 0.020
11 15.665 Isoborneol 1169 0.131 ± 0.012
12 15.951 (-)-Terpinen-4-ol 1178 0.821 ± 0.026
13 16.370 α-Terpineol 1193 0.021 ± 0.010
14 18.032 Thymoquinone 1252 2.296 ± 0.753
15 19.343 Thymol 1294 0.331 ± 0.013
16 20.171 Carvacrol 1326 19.583 ± 1.937
17 21.144 Eugenol 1363 0.042 ± 0.004
18 22.794 Caryophyllene 1430 19.211 ± 2.355
19 23.213 α-Bergamotene 1447 19.529 ± 1.255
20 23.347 (+)-Epi-β-Santalene 1453 0.201 ± 0.014
21 23.627 Humulene 1464 5.636 ± 0.623
22 24.181 (E)-β-Famesene 1486 1.014 ± 0.056
23 24.385 (-)-Zingiberene 1501 0.181 ± 0.068
24 24.548 α-Muurolene 1508 0.478 ± 0.077
25 24.758 β-Bisabolene 1517 2.195 ± 0.079
26 25.108 β-Sesquiphellandrene 1532 1.080 ± 0.039
27 26.034 (±)-trans-Nerolidol 1571 0.033 ± 0.008
28 26.384 Thymohydroquinone 1586 0.213 ± 0.056
29 26.576 Caryophyllene oxide 1594 1.419 ± 0.123
30 27.148 Humulene epoxide II 1615 0.190 ± 0.022
31 28.797 α-Bisabolol 1688 0.039 ± 0.010

a Retention time (RT) in min

b van den Dool and Kratz retention index calculated for HP-5MS column

c Relative peak area expressed as percentage of the peak area of corresponding compound over the total peak areas of all identified volatiles.