| Crystal data |
| Chemical formula |
[Mn(C16H22N4)2O2](C24H20B)2·2H2O |
[Mn(C17H24N4)2O2](C24H20B)2·2C4H10O |
|
M
r
|
1357.08 |
1497.34 |
| Crystal system, space group |
Triclinic, P
|
Monoclinic, P21/n
|
| Temperature (K) |
100 |
100 |
|
a, b, c (Å) |
12.169 (3), 12.404 (4), 13.845 (4) |
15.9472 (16), 13.8380 (14), 17.5219 (17) |
| α, β, γ (°) |
69.752 (7), 67.355 (8), 68.725 (7) |
90, 91.123 (5), 90 |
|
V (Å3) |
1744.7 (8) |
3865.9 (7) |
|
Z
|
1 |
2 |
| Radiation type |
Mo Kα |
Mo Kα |
| μ (mm−1) |
0.42 |
0.39 |
| Crystal size (mm) |
0.15 × 0.05 × 0.05 |
0.1 × 0.05 × 0.05 |
| |
| Data collection |
| Diffractometer |
Bruker APEXII CCD area-detector |
Bruker APEXII CCD area-detector |
| Absorption correction |
Multi-scan (SADABS; Bruker, 2007 ▸) |
Multi-scan (SADABS; Bruker, 2007 ▸) |
|
T
min, T
max
|
0.940, 0.979 |
0.915, 0.947 |
| No. of measured, independent and observed [I > 2σ(I)] reflections |
22505, 8374, 3541 |
138191, 9679, 7420 |
|
R
int
|
0.099 |
0.068 |
| |
| Refinement |
|
R[F
2 > 2σ(F
2)], wR(F
2), S
|
0.073, 0.163, 0.97 |
0.049, 0.134, 1.05 |
| No. of reflections |
8374 |
9679 |
| No. of parameters |
439 |
517 |
| No. of restraints |
6 |
29 |
| H-atom treatment |
H-atom parameters constrained |
H-atom parameters constrained |
| Δρmax, Δρmin (e Å−3) |
0.42, −0.46 |
0.66, −1.01 |
