Table 3.
Uncertainty assessment for the massic activities of 234U, 235U, and 238U in in the natural uranium solution standard SRM 4321d, where u in percent is the relative standard uncertainty for each component. All uncertainty components were evaluated by Assessment Type B, which denotes an evaluation by methods other than statistical methods [6, 7].
| Uncertainty component | u (%) | |||
|---|---|---|---|---|
| 234U | 235U | 238U | ||
| 1 | Uranium mass fraction in CRM 112-A, from CRM 112-A Certificate [5] | 0.003 | 0.003 | 0.003 |
| 2 | Isotopic uranium atom fraction in CRM 112-A, from CRM 112-A Certificate [5] | 0.077 | 0.027 1 | 0.000 20 |
| 3 | Half-life [4] used for conversion of number of atoms to activity | 0.244 | 0.142 | 0.112 |
| 4 | Mass of CRM 112-A uranium metal used | 0.05 | 0.05 | 0.05 |
| 5 | Quantitative dissolution of metal | 0.05 | 0.05 | 0.05 |
| 6 | Mass of SRM 4321d master solution | 0.005 | 0.005 | 0.005 |
| Relative combined standard uncertainty, uc | 0.261 | 0.153 | 0.123 | |
| Relative expanded uncertainty (k = 2), U | 0.52 | 0.31 | 0.25 | |