| N | Components | RIa | RIb | Populations | |||||
|---|---|---|---|---|---|---|---|---|---|
| Daarbast | Konar Siah | Darab | Haneshk | Methods | |||||
| 1 | α-Thujene | 933 | 929 | 0.40 ± 0.24 | 0.43 ± 0.25 | 0.36 ± 0.03 | 0.28 ± 0.17 | RI, MS | |
| 2 | α-Pinene | 940 | 939 | 3.89 ± 2.00 | 3.31 ± 2.50 | 2.62 ± 0.28 | 1.54 ± 0.95 | RI, MS | |
| 3 | Camphene | 955 | 954 | 0.19 ± 0.07 | 0.14 ± 0.07 | 0.15 ± 0.01 | 0.10 ± 0.03 | RI, MS | |
| 4 | 2,4(10)-Thujadiene | 960 | 957 | – | – | – | – | RI, MS | |
| 5 | 1,3-Octanol | 969 | 973 | 0.07 ± 0.01 | 0.15 ± 0.01 | 0.16 ± 0.24 | 0.08 ± 0.02 | RI, MS | |
| 6 | Sabinene | 979 | 977 | 0.11 ± 0.03 | 0.21 ± 0.10 | 0.10 ± 0.01 | 0.10 ± 0.02 | RI, MS | |
| 7 | β-Pinene | 983 | 978 | 0.65 ± 0.28 | 0.56 ± 0.30 | 0.51 ± 0.04 | 0.30 ± 0.13 | RI, MS | |
| 8 | Myrcene | 995 | 992 | 1.10 ± 0.27 | 1.15 ± 0.29 | 0.94 ± 0.11 | 2.34 ± 0.76 | RI, MS | |
| 9 | 3-Octanol | 997 | 995 | 0.18 ± 0.10 | 0.13 ± 0.10 | 0.04 ± 0.01 | 0.16 ± 0.09 | RI, MS | |
| 10 | α-Phellandrene | 1010 | 1005 | 0.18 ± 0.01 | 0.18 ± 0.01 | 0.13 ± 0.01 | 0.34 ± 0.11 | RI, MS | |
| 11 | δ-3-Carene | 1015 | 1011 | 0.03 ± 0.01 | 0.02 ± 0.01 | – | – | RI, MS | |
| 12 | α-Terpinene | 1021 | 1019 | 1.15 ± 0.15 | 1.25 ± 0.25 | 1.04 ± 0.06 | 0.81 ± 0.41 | RI, MS | |
| 13 | p-Cymene | 1030 | 1025 | 6.34 ± 2.69 | 6.42 ± 2.21 | 13.96 ± 1.1 | 4.33 ± 2.76 | RI, MS | |
| 14 | Limonene | 1034 | 1030 | 0.58 ± 0.27 | 0.58 ± 0.27 | 0.61 ± 0.09 | 0.76 ± 0.13 | RI, MS | |
| 15 | 1,8-Cineole | 1037 | 1035 | 0.06 ± 0.01 | 0.06 ± 0.01 | 0.07 ± 0.05 | 0.19 ± 0.16 | RI, MS | |
| 16 | Z-β-Ocimene | 1039 | 1039 | 0.52 ± 0.30 | 0.59 ± 0.33 | 0.45 ± 0.04 | 0.68 ± 0.30 | RI, MS | |
| 17 | E-β-Ocimene | 1050 | 1050 | 0.08 ± 0.02 | 0.09 ± 0.03 | 0.04 ± 0.02 | 0.94 ± 0.50 | RI, MS | |
| 18 | γ-Terpinene | 1063 | 1062 | 4.73 ± 0.97 | 4.79 ± 1.03 | 2.93 ± 0.24 | 2.60 ± 1.76 | RI, MS | |
| 19 | Z-Sabinene hydrate | 1071 | 1070 | 0.20 ± 0.04 | 0.25 ± 0.05 | 0.21 ± 0.01 | 0.33 ± 0.27 | RI, MS | |
| 20 | Z-Linalool oxide | 1076 | 1074 | 0.10 ± 0.01 | 0.04 ± 0.01 | 0.04 ± 0.02 | 0.45 ± 0.30 | RI, MS | |
| 21 | Terpinolene | 1092 | 1089 | 0.21 ± 0.04 | 0.23 ± 0.06 | 0.21 ± 0.03 | 0.78 ± 0.28 | RI, MS | |
| 22 | Linalool | 1103 | 1100 | 1.25 ± 0.70 | 1.73 ± 1.10 | 1.69 ± 0.97 | 37.65 ± 20.6 | RI, MS | |
| 23 | E-γ-Caryophyllene | 1106 | 1106 | 0.06 ± 0.02 | 0.09 ± 0.06 | 0.10 ± 0.04 | 0.93 ± 0.50 | RI, MS | |
| 24 | 1-Octenyl-3-acetate | 1111 | 1113 | 0.03 ± 0.01 | 0.07 ± 0.06 | – | 0.11 ± 0.07 | RI, MS | |
| 25 | p-Menth-2-en-1-ol | 1124 | 1122 | 0.04 ± 0.03 | tr | – | 0.16 ± 0.10 | RI, MS | |
| 26 | allo-Ocimene | 1131 | 1132 | – | – | – | 0.38 ± 0.26 | RI, MS | |
| 27 | 1,3,8-p-Menthatriene | 1133 | – | – | – | 0.10 ± 0.08 | MS | ||
| 28 | Borneol | 1172 | 1171 | – | – | – | 0.99 ± 0.68 | RI, MS | |
| 29 | Z-Linalool oxide (pyranoid) | 1177 | 1173 | – | tr | 0.12 ± 0.02 | 0.13 ± 0.06 | RI, MS | |
| 30 | 4-Terpineol | 1183 | 1179 | 0.19 ± 0.04 | 0.16 ± 0.05 | 0.18 ± 0.02 | 0.18 ± 0.05 | RI, MS | |
| 31 | p-Cymenol-8 | 1188 | 1184 | 0.48 ± 0.07 | 0.48 ± 0.05 | 0.59 ± 0.03 | 0.29 ± 0.09 | RI, MS | |
| 32 | α-Terpineol | 1195 | 1190 | 0.72 ± 0.37 | 0.81 ± 0.40 | 0.58 ± 0.04 | 0.60 ± 0.09 | RI, MS | |
| 33 | Z-Dihydro carvone | 1202 | 1200 | 0.19 ± 0.04 | 0.17 ± 0.08 | 0.03 ± 0.02 | 0.21 ± 0.11 | RI, MS | |
| 34 | Nerol | 1234 | 1228 | 0.02 ± 0.01 | – | 0.02 ± 0.01 | 0.06 ± 0.04 | RI, MS | |
| 35 | Thymol methyl ether | 1238 | 1237 | 0.08 ± 0.01 | 0.10 ± 0.08 | 1.52 ± 0.12 | 0.59 ± 0.50 | RI, MS | |
| 36 | Carvacrol methyl ether | 1248 | 1241 | 3.71 ± 3.00 | 3.23 ± 3.00 | 1.62 ± 0.38 | 0.92 ± 0.72 | RI, MS | |
| 37 | Geraniol | 1260 | 1263 | tr | 0.02 ± 0.01 | tr | 0.60 ± 0.28 | RI, MS | |
| 38 | Geranial | 1280 | 1273 | – | – | – | – | RI, MS | |
| 39 | p-Thymol | 1286 | 0.09 ± 0.05 | 0.07 ± 0.01 | 0.22 ± 0.03 | 0.05 ± 0.04 | MS | ||
| 40 | Thymol | 1295 | 1295 | 5.26 ± 3.85 | 8.65 ± 8.30 | 41.61 ± 4.14 | 17.55 ± 10.9 | RI, MS | |
| 41 | Carvacrol | 1309 | 1305 | 61.41 ± 13.3 | 58.29 ± 13.3 | 21.81 ± 4.91 | 15.74 ± 12.9 | RI, MS | |
| 42 | Thymol acetate | 1358 | 1359 | 0.10 ± 0.10 | 0.17 ± 0.13 | 0.75 ± 0.09 | 0.21 ± 0.13 | RI, MS | |
| 43 | Carvacrol acetate | 1377 | 1368 | 1.12 ± 0.61 | 1.45 ± 1.23 | 0.31 ± 0.09 | 0.20 ± 0.09 | RI, MS | |
| 44 | β-Bourbonene | 1384 | 1378 | – | – | – | 0.04 ± 0.03 | RI, MS | |
| 45 | E-Caryophyllene | 1435 | 1427 | 1.93 ± 0.62 | 1.59 ± 0.36 | 1.59 ± 0.38 | 1.71 ± 0.62 | RI, MS | |
| 46 | Aromadendrene | 1455 | 1436 | 0.47 ± 0.07 | 0.38 ± 0.16 | 0.24 ± 0.09 | 0.19 ± 0.11 | RI, MS | |
| 47 | α-Humulene | 1469 | 1452 | 0.14 ± 0.02 | 0.12 ± 0.03 | 0.11 ± 0.02 | 0.16 ± 0.04 | RI, MS | |
| 48 | 9-epi-(E)-Caryophyllene | 1477 | 1474 | 0.03 ± 0.01 | 0.03 ± 0.03 | – | tr | RI, MS | |
| 49 | E-β-Guaiene | 1504 | 1498 | 0.02 ± 0.01 | tr | – | – | RI, MS | |
| 50 | Viridiflorene | 1510 | 1505 | 0.38 ± 0.13 | 0.32 ± 0.18 | 0.14 ± 0.05 | 0.36 ± 0.15 | RI, MS | |
| 51 | Spathulenol | 1594 | 1578 | 0.48 ± 0.24 | 0.44 ± 0.24 | 0.35 ± 0.05 | 0.77 ± 0.31 | RI, MS | |
| 52 | Isoaromadendrene epoxide | 1597 | 0.10 ± 0.03 | 0.09 ± 0.04 | 0.21 ± 0.02 | 0.27 ± 0.10 | MS | ||
| 53 | Caryophyllene oxide | 1601 | 1599 | 0.21 ± 0.04 | 0.20 ± 0.07 | 0.35 ± 0.03 | 0.45 ± 0.13 | RI, MS | |
| 54 | Caryophylla-4(12),8(13)-dien-5 beta-ol | 1654 | 1663 | 0.09 ± 0.02 | 0.07 ± 0.05 | 0.12 ± 0.01 | 0.21 ± 0.06 | RI, MS | |
| 55 | 14-Hydroxy-9-epi-(E)-caryophyllene | 1673 | 1669 | 0.07 ± 0.03 | 0.05 ± 0.04 | 0.13 ± 0.01 | 0.16 ± 0.06 | RI, MS | |
| 56 | Khusinol | 1686 | 1674 | 0.08 ± 0.02 | 0.06 ± 0.04 | 0.12 ± 0.01 | 0.17 ± 0.05 | RI, MS | |
| Monoterpene hydrocarbons | 20.16 | 19.95 | 24.05 | 16.38 | |||||
| Oxygenated monoterpens | 75.05 | 75.75 | 71.37 | 77.21 | |||||
| Sesquiterpene hydrocarbons | 3.03 | 2.53 | 2.18 | 3.39 | |||||
| Oxygenated sesquiterpenes | 1.03 | 0.91 | 1.28 | 2.03 | |||||
| Essential oil content (%) | 5.58 ± 0.48 | 5.89 ± 0.24 | 3.3 ± 0.26 | 3.71 ± 0.41 | |||||
tr, trace < 0.02%.
a: RI, linear retention indices on HP-5MS column, experimentally determined using homologue series of n-alkanes.
b: Relative retention indices taken from Adams and NIST.
Methods: MS, by comparison of the mass spectrum with those of the computer mass libraries Adams and NIST.