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Thermodynamic parameters of the complex formation between TAC and MTX
| Experiments | Modeling | ||||
|---|---|---|---|---|---|
| Temperature (K) | ΔH (kJ mol−1) |
ΔS (J K−1 mol−1) |
Structure (see Figure 5) |
ΔH (kJ mol−1) |
ΔS (J K−1 mol1) |
| 293.15–299.82 | 15.79 ± 0.7 | 133.56 ± 6 | closed | 8.43 | 126.11 |
| 303.15–313.15 | −210.66 ± 1.7 | −614.57 ± 12 | opened | −154.42 | −214.67 |
ΔH and ΔS are the enthalpy change and entropy change, respectively.
