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. Author manuscript; available in PMC: 2021 Apr 22.
Published in final edited form as: Chem Rev. 2020 Mar 27;120(8):3749–3786. doi: 10.1021/acs.chemrev.9b00717

Table 8.

Enzymatic fuel cells using at least one soluble mediator in the anode or cathode.

Anode Cathode
fuel catalyst mediator mediator catalyst oxidant ref
H2 Pt – ABTS2− laccase O2 146
Desulfovibrio vulgaris viologen bilirubin oxidase 149
glucose glucose oxidase Fc(CH2OH) bilirubin oxidase or laccase 147–151
glucose glucose oxidase/AuNP-graphene – laccase/AuNP-graphene 152
BPA laccase – laccase 153
glucose glucose dehydrogenase PS-βCD-PQ PS-βCD-P2ABTS bilirubin oxidase 154
MeOH methanol dehydrogenase PMS or PES – Pt 184–185
MeOH quinoprotein alcohol dehydrogenase TMPD 186
glucose glucose oxidase Os polymer laccase 188
MeOH multi-enzyme cascade BV2+ +NADH – Pt 190
glucose glucose oxidase DCIP 189
quinone 195
glucose-6-phosphate G6PDH and diaphorase quinone + NADH 196
MeOH alcohol dehydrogenase TMPD – KMnO4 187
H2 NiFe hydrogenase MV2+ MV2+ MoFe Nitrogenase N2 193