Table 3.
Molecular Weight Distribution Data & Glass Transition for PFS/MMA copolymers.
FPFS 1) |
|
|
|
Đ 3) |
Tg
4)
|
---|---|---|---|---|---|
0.08 | 0.0767 | 21,100 | 25,310 | 1.20 | 110 |
0.18 | 0.0706 | 14,720 | 18,970 | 1.29 | 107 |
0.32 | 0.0632 | 13,790 | 15,860 | 1.15 | 100 |
0.57 | 0.0529 | 10,650 | 11,910 | 1.13 | 90 |
0.81 | 0.0455 | 10,550 | 13,060 | 1.24 | 88 |
0.89 | 0.0435 | 51,700 | 73,250 | 1.42 | 84 |
1.00 | 0.0411 | 17,400 | 19,900 | 1.14 | 79 |
1) Final molar copolymer composition, 2) used was weight average of the homopolymers (0.0411 for poly(PFS) and 0.0831 for poly(MMA)) 3) Number-average molecular weight (), weight-average molecular weight () and the dispersity (Đ = Mw/Mn) were determined by gel permeation chromatography (GPC)*. 4) glass transition temperature determined by differential scanning calorimetry (DSC).