Table 1.
Entry | R | Product | Time (min) | Yielda (%) | Melting point (°C) Observed |
Melting point (°C) Reported |
---|---|---|---|---|---|---|
1 | Benzaldehyde | 4a | 18 | 91 | 277–279 | 278–28057 |
2 | 4-Chlorobenzaldehyde | 4b | 18 | 88 | 262–265 | 262–26457 |
3 | 2-Chlorobenzaldehyde | 4c | 25 | 84 | 196–198 | 196–19835 |
4 | 3-Chlorobenzaldehyde | 4d | 26 | 81 | 296–298 | 296–29758 |
5 | 2,4-Dichlorobenzaldehyde | 4e | 28 | 89 | 174–177 | 176–17835 |
6 | 2,6-Dichlorobenzaldehyde | 4f | 33 | 84 | 236–238 | 236–23859 |
7 | 4-Bromobenzaldehyde | 4 g | 27 | 87 | 265–267 | 264–26660 |
8 | 4-Methoxybenzaldehyde | 4 h | 30 | 86 | 232–234 | 233–23461 |
9 | 3,4,5-Trimethoxybenzaldehyde | 4i | 33 | 82 | 259–261 | 261–26262 |
10 | 2-Methoxybenzaldehyde | 4j | 35 | 85 | 210–212 | 209–21163 |
11 | 4-Methylbenzaldehyde | 4 k | 33 | 88 | 231–233 | 230–23264 |
12 | 4-Hydroxybenzaldehyde | 4 l | 38 | 87 | 261–263 | 260–26265 |
13 | 2-Nitrobenzaldehyde | 4 m | 30 | 86 | 231–233 | 230–23263 |
14 | 4-Nitrobenzaldehyde | 4n | 26 | 84 | 234–236 | 235–23866 |
15 | 4-Fluorobenzaldehyde | 4o | 32 | 92 | 248–250 | 247–24967 |
16 | Furfural | 4p | 29 | 90 | 237–239 | 237–23968 |
aIsolated yield.