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. Author manuscript; available in PMC: 2020 Oct 21.
Published in final edited form as: Chem Soc Rev. 2020 Jun 8;49(14):4906–4925. doi: 10.1039/c9cs00740g

Fig. 13.

Fig. 13

Mechanism of C-F bond cleavage promoted by CDO. Ferric superoxide is regenerated after cofactor biogenesis, and it proceeds with the dioxygenation of the ligated substrate, forming CSA as the product.