Table 3. Calculated Kinetic Parameters of the Reaction between HU2– and Selected Radicals Following the SET-2 Mechanism in Aqueous Solution at pH 7.4a.
| radical | ΔG⧧ | λ | kD | kapp | kf |
|---|---|---|---|---|---|
| HO• | 3.9 | 5.7 | 8.40 × 109 | 4.10 × 109 | 1.60 × 108 |
| CH3O• | 2.8 | 7.7 | 8.10 × 109 | 7.10 × 109 | 2.77 × 108 |
| CCl3O• | 0.2 | 54.8 | 7.60 × 109 | 7.60 × 109 | 2.96 × 108 |
| HOO• | 9.5 | 17.2 | 8.20 × 109 | 7.20 × 105 | 2.81 × 104 |
| CH3OO• | 11.0 | 16.6 | 8.00 × 109 | 5.80 × 104 | 2.26 × 103 |
| CCl3OO• | 0.5 | 18.3 | 6.80 × 109 | 6.80 × 109 | 2.65 × 108 |
| NO | 96.4 | 16.2 | 8.40 × 109 | 1.30 × 10–58 | 5.07 × 10–60 |
| NO2 | 2.0 | 30.0 | 8.20 × 109 | 7.80 × 109 | 3.04 × 108 |
| O2•– | 55.3 | 19.1 | 8.60 × 109 | 1.80 × 10–28 | 7.02 × 10–30 |
| SO4•– | 3.0 | 21.0 | 7.80 × 109 | 6.50 × 109 | 2.54 × 108 |
| N3• | 2.7 | 4.9 | 8.10 × 109 | 7.10 × 109 | 2.77 × 108 |
kf = f × kapp, f(H2UA2–) = 0.039.