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. 2020 Jul 8;5(28):17664–17671. doi: 10.1021/acsomega.0c02192

Table 3. Apparent Rate Constants K1, K2, and K3 and Correlation Coefficients.

  liquid boundary layer diffusion
diffusion through the product layer
surface chemical reaction
  X
1 – 2/3x – (1 – x)2/3
1 – (1 – x)1/3
temperature (°C) K1 (min–1) R2 K2 (min–1) R2 K3 (min–1) R2
50 0.000862 0.9292 0.000058 0.9488 0.000348 0.9924
60 0.001690 0.9389 0.000207 0.9324 0.000791 0.9938
70 0.002540 0.9121 0.000597 0.9115 0.001560 0.9929
80 0.001900 0.9377 0.000663 0.9545 0.001480 0.9943
90 0.002050 0.9245 0.000921 0.9800 0.001950 0.9932