Table 3. Apparent Rate Constants K1, K2, and K3 and Correlation Coefficients.
| liquid
boundary layer diffusion |
diffusion
through the product layer |
surface
chemical reaction |
||||
|---|---|---|---|---|---|---|
|
X |
1 – 2/3x – (1 – x)2/3 |
1 – (1 – x)1/3 |
||||
| temperature (°C) | K1 (min–1) | R2 | K2 (min–1) | R2 | K3 (min–1) | R2 |
| 50 | 0.000862 | 0.9292 | 0.000058 | 0.9488 | 0.000348 | 0.9924 |
| 60 | 0.001690 | 0.9389 | 0.000207 | 0.9324 | 0.000791 | 0.9938 |
| 70 | 0.002540 | 0.9121 | 0.000597 | 0.9115 | 0.001560 | 0.9929 |
| 80 | 0.001900 | 0.9377 | 0.000663 | 0.9545 | 0.001480 | 0.9943 |
| 90 | 0.002050 | 0.9245 | 0.000921 | 0.9800 | 0.001950 | 0.9932 |