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A) AtGALS1‐catalyzed transfer of azido‐ (1 and 2) and amino‐functionalized (5 and 6) UDP‐Gal derivatives to selected oligosaccharides on the array. B) Printing pattern for the synthetic plant glycan array. Azide controls were printed in the bottom right corner of the array in 10, 100, 200, and 400 μm concentrations. Subset of β‐1,4‐linked galactan acceptor substrates is shown.
