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. 2020 Jun 3;59(30):12493–12498. doi: 10.1002/anie.202003105

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© 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.

This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.

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A) Glycan array‐based characterization of plant GTs PtGALS1, AtGALS2, AtGalT31A, and fucosyltransferases AtFUT4, AtFUT6, and AtFUT7. B) Glycan array‐based characterization of xylosyltransferase AtXXT1. AtXXT1 and AtGALS1 show loose donor substrate specificity and accept functionalized UDP‐Gal and UDP‐Xyl donors, respectively. C) Selected human galactosyl‐ and fucosyltransferases recognize not only their natural acceptor substrates, but also fungal and plant cell wall oligosaccharides. Subset of acceptor glycans is shown. The full set of printed glycans is presented in Supplementary Figure 1 (see the Supporting Information).