Table 10.

Comparison of the ¹³C NMR resonances of the terminal units in 11, 17, and 19 with those of the corresponding carbons in 2 and 5^a.

No	2	5	11	11vs2	11vs5	17	17vs2	17vs5	19	19vs2	19vs5
	δC	δC	δC	ΔδC	ΔδC	δC	ΔδC	ΔδC	δC	ΔδC	ΔδC
2	84.43	83.80	84.44	0.01	0.64	85.1	0.67	1.3	84.49	0.06	0.69
3	68.09	68.32	68.08	−0.01	−0.24	68.18	0.09	−0.14	68.13	0.04	−0.19
4	29.04	28.84	29.18	0.14	0.34	29.22	0.18	0.38	29.14	0.10	0.30
5	156.15	156.14	156.09	−0.06	−0.05	156.15	0	0.01	155.98	−0.17	−0.16
6	96.39	96.37	96.30	−0.09	−0.07	96.60	0.21	0.23	96.45	0.05	0.07
7	152.19	152.17	152.11	−0.08	−0.06	152.08	−0.11	−0.09	152.52	0.33	0.35
8	106.69	106.4	106.79	0.10	0.39	106.39	−0.3	−0.01	107.12	0.43	0.72
9	151.41	150.80	151.36	−0.05	0.56	151.29	−0.12	0.49	151.00	−0.41	0.20
10	103.01	102.69	103.11	0.10	0.42	103.08	0.07	0.39	102.80	−0.22	0.11
1’	130.47	130.77	130.37	−0.10	−0.40	129.95	−0.52	−0.82	130.43	−0.04	−0.34
2’	115.65	115.30	115.83	0.18	0.53	116.31	0.66	1.01	115.70	0.05	0.40
3’	146.30	146.35	146.21	−0.09	−0.14	146.11	−0.19	−0.24	146.20	−0.10	−0.15
4’	146.74	146.70	146.70	−0.04	0.00	146.92	0.18	0.22	146.70	−0.04	0.00
5’	116.22	116.24	116.28	0.06	0.04	116.78	0.56	0.54	116.00	−0.22	−0.24
6’	120.66	120.30	120.81	0.15	0.51	121.31	0.65	1.01	120.74	0.08	0.44
ΣΔδC				√0.22	2.47		√2.03	4.28	84.49	√−0.06	2.19

^aThe ¹³C NMR data (100 MHz) was acquired in CD₃OD with the temperature set as 278 K. ^√With smaller ΣΔδ_C value.