Table 1.
Arrhenius parameters obtained from the temperature-dependence of the rotational correlation times of TEMPOL at 0.5, 1.0, 2.0 and 4.0 % v/v DMSO, in Region III.
Ea (kcal/mol) | |||
---|---|---|---|
DMSO (% v/v) | +EAL PAD | +EAL mesodomain | -EAL mesodomain |
0.5 | 13 ±0.61 | 8.5 ±0.20 | 8.6 ±0.39 |
1.0 | 11 ±0.73 | 9.0 ±0.32 | 8.7 ±0.28 |
2.0 | 9.2 ±0.40 | 7.9 ±0.23 | 9.0 ±0.42 |
4.0 | 9.0 ±0.31 | 8.5 ±0.12 | 8.5 ±0.22 |
-log[τc,0 (s)] | |||
DMSO (% v/v) | +EAL PAD | +EAL Mesodomain | -EAL Mesodomain |
0.5 | 20 ±0.57 | 17 ±0.19 | 17 ±0.37 |
1.0 | 19 ±0.70 | 17 ±0.30 | 17 ±0.27 |
2.0 | 17 ±0.39 | 16 ±0.22 | 17 ±0.40 |
4.0 | 17 ±0.31 | 17 ±0.12 | 16 ±0.21 |