Table 1. Reductive Hydroboration of Nitriles Catalyzed by 3aa.
Reaction conditions: 0.33 mmol substrate, 0.72 mmol HBpin (2.2 equiv), 3a (4 mol %), 1 mL of benzene.
Isolated yields as hydrochloride.
Conversion determined by 19F{1H} NMR spectroscopy.
Reaction conditions: 0.33 mmol substrate, 0.72 mmol HBpin (2.2 equiv), 3a (4 mol %), 1 mL of benzene.
Isolated yields as hydrochloride.
Conversion determined by 19F{1H} NMR spectroscopy.