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. Author manuscript; available in PMC: 2020 Dec 22.
Published in final edited form as: Nat Chem. 2020 Jun 22;12(8):697–704. doi: 10.1038/s41557-020-0482-8

Table 1.

Synthetic scope of alcohols in enantioselective, radical C–H amination.

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Conditions: 1% Ir{[dF(CF3)ppy]2dtbbpy}BArF4, 2% CuBArF4, 4% ligand L1, 25% camphoric acid, pentane: Et2O (2:1), blue LED irradiation, room temperature, 1 hour. See General Procedure 3 in SI section II for full experimental details. Isolated yield and enantiomeric excess (e.e.) indicated below each entry.