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. 2020 Jul 15;5(29):18301–18312. doi: 10.1021/acsomega.0c01965

Table 3. Reaction with Ethylene after ADMET Polymerizationa.

      ADMET polymerizationb
reaction with ethylened
run monomer cat. time/h Mnc Mw/Mnc Mnc Mw/Mnc yielde/%
44 ME1 HG2 12 10,200 1.39 2000 1.51 87
45 ME1 G2 12 9800 1.55 1800 1.46 88
46 ME1 G2 6 8400 1.62 1500 1.54 85
47 ME2 HG2 12 10,800 1.46 2200 1.45 89
48 ME2 G2 12 11,300 1.45 1600 1.45 89
49 ME2 G2 6 8500 1.54 1400 1.48 84
a

Conditions: Ru cat. 2.0 mol % and monomer 300 mg in CHCl3 0.14 mL. 50 °C.

b

ADMET polymerization at 50 C.

c

GPC data in THF versus polystyrene standards.

d

Ethylene 0.8 MPa at 50 °C for 1 h.

e

Isolated yield as MeOH insoluble fraction.