TABLE 1.
Summary of Gibbs free energy change in sulfur reactions#.
Rct. No. | Chemical reaction | ΔG0′ (kJ) | ΔG0 at pH 10 (kJ) | References |
1 | Acetate– + 4S0 + 4H2O → 4HS– + 2HCO3– + 5H+ | −6.6 | −91.9 | Oren, 2011 |
2 | Acetate– + 4S4O62– + 4H2O → 2HCO3– + 9H+ + 8S2O32– | −233.4 | −386.94 | Thauer et al., 1977 |
3 | Acetate– + SO42– → 2HCO3– + HS– | −47.3 | −47.3 | Thauer et al., 1977 |
4 | 4H2 + SO42– + H+ → HS– + 4H2O | −151.9 | −134.84 | Thauer et al., 1977 |
#The ΔG values were calculated using acetate or hydrogen as samples and presented as the Gibbs free energy change per reaction. Eight electrons were transferred in every reaction.