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. 2020 Jul 28;6(7):e04559. doi: 10.1016/j.heliyon.2020.e04559

Table 2.

Identification of residual organic pollutants by GC-MS from TMS derivatized DCM extract from pulp and paper industry effluent sludge discharge after secondary treatment.

Before phytoextraction RT Compounds % similarity with NIST Toxicity
6.06 2-Pentadecanone 75 Hazardous to the aquatic environment, long-term hazard
10.27 Nonacosane 94 Oral, dermal and inhalation toxicity
21.91 Benzene Propanoic acid, tert-butyldimethylsilyl ester 59 Genotoxicity
25.53 Octadecanoic acid, TMS 92 Endocrine disrupting chemicals (EDCs)
28.10 Tetradecanoic methyl ester 95 EDCs, genotoxicity
31.82 Heptacosane 91 EDCs
33.81 Hexadecanoic acid, TMS 97 EDCs, mutagenic
35.60 D-Lactic acid- DITMS 89 Genotoxicity
40.27 Lactic acid, TMS ether, TMS 93 Genotoxicity
42.19 Cinnamic acid-α-phenyl-TMS ester 96 Genotoxicity
43.77 β- Sitosterol TMS 98 EDCs, genotoxicity, Mutagenic
47.01 4-Mercaptobenzoic acid 86 Carcinogenic

After phytoextraction RT Compounds % similarity with NIST Toxicity

6.31 Pentatonic acid, TMS ester 91 Long-term hazard
19.39 1,4-Bis (hexadecyl)-2,5-divinylbenzene 78 Serious eye damage/eye irritation
21.76 O-Trimethylsilyl Pyridine-2-Amidoxime 81 Unknown
27.68 6-Acetyl-1-acetoxy-10-hydroxy-neoline 83 Data not known
30.56 1-Methyl-3-(3,4-dimethoxyphenyl)-6,7-dimethoxyisochromene 78 Data not known
42.99 Decane, 1 bromo-2-methy 71 Data not known

TMS: Trimethylsilyl; RT: Retention Time (Min).