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. Author manuscript; available in PMC: 2021 Aug 3.
Published in final edited form as: Angew Chem Int Ed Engl. 2020 Jun 2;59(32):13406–13413. doi: 10.1002/anie.202005300

Table 1.

Product studies upon anaerobic photolysis of 1 in the presence of acetone (2% v/v) as sensitizer.[a]

Reducing Agent (mM) % Yield dG[b] % Mass Balance[b]
Fe2+ (10) 85 ± 2 90 ± 1
PhSH (10) 89 ± 3 93 ± 1
BME (10) 87 ± 2 91 ± 2
None[c] 55 ± 3 65 ± 1
None[d] 35 ± 2 44 ± 3
[a]

[1] = 0.1 mM.

[b]

Average ± std. dev. of 3 experiments.

[c]

Anaerobic photolysis.

[d]

Aerobic photolysis