TABLE 1.
Analytes | RT (min) | Transition | CV (v) | CE (v) | Molecular weight | Actual concentration (μg/g) |
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Maize | Soybean | Control | ||||||
p-Hydroxybenzoic acid | 0.85 | 136.968>93.476 | 28 | 32 | 137 | 17.11 ± 0.78a | 3.29 ± 1.43b | 0.82 ± 0.38c |
p-Coumaric acid | 1.34 | 162.968>119.468 | 28 | 32 | 164 | 26.13 ± 0.12 | – | – |
Cinnamic acid | 2.80 | 147.032>76.967 | 26 | 30 | 148 | 0.15 ± 0.02 | – | – |
Vanillic acid | 0.97 | 166.968>151.995 | 14 | 30 | 168 | 4.93 ± 0.13a | 1.55 ± 0.10b | 0.11 ± 0.02c |
Ferulic acid | 1.56 | 193.032>133.979 | 16 | 30 | 194 | 0.51 ± 0.00b | 2.16 ± 0.06a | 0.04 ± 0.02c |
RT, retention time; CV, cone voltage; CE, collision energy. Control, soil without plant culture. The error indicates the standard errors of the means (n = 3). Significant differences are based on ANOVA tests. Lower case letters show significant differences in the same phenolic acids at the soil with different plant culture at the 0.05 level.