Table 1.
Sample | Reactants (mmol) | Catalyst (mmol) | Zn (mmol) | BPY (mmol) | PPh3 (mmol) | Mn a (kDa) | Mw a (kDa) | PDI |
---|---|---|---|---|---|---|---|---|
NiBr2 | 6.4 | 0.5 | 27.5 | - | 3.2 | 1.3 | 2.0 | 1.6 |
NiCl2 | 6.4 | 0.5 | 27.5 | - | 3.2 | 1.5 | 2.3 | 1.6 |
Ni(COD)2 | 2.9 | 7.2 | - | 7.2 | - | 1.4 | 2.4 | 1.7 |
a Estimated by GPC analyses (calibrated with polystyrene standards).