Table 5.
Thermodynamic parameters for phosphate and nitrate removal by SBAC100MgFe composite at pH 3 and pH 6.
T (K) | Kd | ΔG (kJ/mol) | ΔH (kJ/mol) | ΔS (J/mol K) | |
---|---|---|---|---|---|
Phosphate (pH 3) |
298 | 30.0 | −8.43 | ||
308 | 31.8 | −8.86 | 5.30 | 46.0 | |
318 | 34.3 | −9.35 | |||
Phosphate (pH 6) |
298 | 12.6 | −6.27 | ||
308 | 15.5 | −7.01 | 11.8 | 60.7 | |
318 | 16.9 | −7.48 | |||
Nitrate (pH 3) |
298 | 4.35 | −3.64 | ||
308 | 4.50 | −3.85 | 4.90 | 28.5 | |
318 | 4.92 | −4.21 | |||
Nitrate (pH 6) |
298 | 1.36 | −0.76 | ||
308 | 1.95 | −1.71 | 18.8 | 65.8 | |
318 | 2.18 | −2.06 |