Table 1. Product Yields of the Substrate Variation Experiments under Oxygen Atmosphere Reaction Conditions: 2 mmol of Substrate, 0.5 mmol of (Vanadium Content) H6[PV3Mo9O40] Catalyst, 10 g of Water, 160 °C Reaction Temperature, 20 bar Oxygen Pressure, 1000 rpm Stirrer Speed, 1 h Reaction Timea.
| entry | substrate | YFA (%) | YAA (%) | Yglyceral (%) | YCO2 (%) | YCO (%) | X (%) |
|---|---|---|---|---|---|---|---|
| 1 | glycose | 36.0 | 7.9 | 3.9 | 27.6 | 1.2 | 100 |
| 2 | xylose | 39.5 | 7.7 | 0 | 25.6 | 1.3 | 100 |
| 3 | glyceraldehyde | 41.7 | 16.1 | 0 | 22.5 | 2.4 | 100 |
| 4 | dihydroxyacetone | 33.6 | 18.8 | 0 | 20.9 | 1.0 | 100 |
| 5 | glycolaldehyde | 35.1 | 0 | 0 | 8.7 | 1.9 | 100 |
| 6 | glyoxal | 29.0 | 0 | 0 | 5.2 | 0 | 100 |
Abbreviations: formic acid (FA); acetic acid (AA); glyceraldehyde (glyceral).