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. 2020 Jul 24;5(30):19082–19091. doi: 10.1021/acsomega.0c02430

Table 2. Product Yields of the Substrate Variation Experiments under Nitrogen Atmosphere Reaction Conditions: 2 mmol of Substrate, 0.5 mmol of (Vanadium Content) K5[V3W3O19] Catalyst, 10 g of Water, 160 °C Reaction Temperature, 20 bar Nitrogen Pressure, 1000 rpm Stirrer Speed, 1 h Reaction Timea.

entry substrate YFA (%) YAA (%) YLA (%) YHMF (%) YLevA (%) Yglyceral (%) YPA (%) Yglycolal (%) YCO2 (%) X (%)
1 glycose 7.5 7.2 17.3 3.7 3.2 8.1 2.5 0 2.0 90.5
2 xylose 6.8 5.1 15.4 0.6 1.9 4.2 1.0 0 2.1 93.6
3 glyceraldehyde 6.2 8.3 17.9 0.5 2.5 7.7 2.4 0 2.8 92.3
4 dihydroxyacetone 4.9 9.3 17.6 0 3.2 6.2 1.7 0 3.4 100
5 glycolaldehyde 14.2 7.3 0 0 1.9 5.9 2.4 14.1 0 78.8
6 glyoxal 14.7 0 0 0 0 0 0 20.6 0 99.0
a

Abbreviations: formic acid (FA); acetic acid (AA); lactic acid (LA), hydroxymethylfurfural (HMF); levulinic acid (LevA); glyceraldehyde (glyceral); propionic acid (PA); glycolaldehyde (glycolal).