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. Author manuscript; available in PMC: 2021 Jul 6.
Published in final edited form as: Angew Chem Int Ed Engl. 2020 May 11;59(28):11364–11368. doi: 10.1002/anie.202004464

Scheme 3.

Scheme 3.

a) Proposed dynamic kinetic resolution process through an enantioselective aza-MBH reaction. b) Optimization of the chiral sulfide used for enantioselective cyclization.