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(a) [XeF5]+ cations and [Ti10F45]5− anions, composed of ten TiF6 octahedra, in β-[XeF5]5[Ti10F45]. Ref. [35]; reproduced by permission of The Royal Society of Chemistry (RSC) on behalf of the Centre National de la Recherche Scientifique (CNRS) and the RSC; (b) Geometry of the [Ti10F45]5− anion (Figure was made by Z.M. using crystallographic data from CIF-file of β-[XeF5]5[Ti10F45] [35]).
