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. 2020 Jul 7;25(13):3092. doi: 10.3390/molecules25133092

Table 1.

Kinetic model parameters of phosphorus adsorption on alumina adsorbents.

Parameter SB-500 GA-1-500 GA-2-500
Pseudo-first-order
dqtdt=k1(qeqt)
qe,exp (mg·g−1) 48.9 99.6 82.3
qe,cal (mg·g−1) 14.6 2.6 11.3
k1 (10−2·min−1) 1.13 3.04 3.998
R2 0.660 0.588 0.852
Pseudo-second-order
dqtdt=k2(qeqt)2
qe,cal (mg·g−1) 49.0 99.7 82.6
k2 (10−2·g·mg−1·min−1) 0.34 7.03 1.47
R2 0.998 0.999 0.999

where t is the adsorption time (min); qe and qt are the amounts adsorbed at the equilibrium state and at given time t, respectively (mg·g−1); k1 (min−1) and k2 (g·mg−1·min−1) represents the rate constants of the pseudo-first-order and pseudo-second-order kinetic adsorption, respectively; qe,exp and qe,cal is the experimental and calculated values of qe.