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. Author manuscript; available in PMC: 2020 Aug 7.
Published in final edited form as: Inorg Chem. 2020 Jan 28;59(4):2178–2187. doi: 10.1021/acs.inorgchem.9b02758

Table 2:

Time constants for CO release (τ1) and solvent coordination (τ2) a

Compound τ1 (ps) τ2 (ps)
1 0.50 ± 0.10 39 ± 4
2 0.46 ± 0.10 30 ± 4
3 0.68 ± 0.20 18 ± 3
a

From global fits to the TA spectra for ~2 mM solutions of 1-3 in MeCN.