Table 2.
Foaming Method | Foaming Agent | Aluminosilicate Sources | Alkaline Activator | Curing Conditions | Results | Ref. | ||
---|---|---|---|---|---|---|---|---|
T (°C) | T (h) | RH (%) | ||||||
Chemical foaming | Al powder | Fly ash | Sodium hydroxide and sodium silicate | 60 | 24 | n.r. | The ratio of alkaline activators impacts the extent of foaming. | [35] |
Chemical foaming | Al powder | Fly ash | Sodium hydroxide | 60 | 24 | n.r. | Al powder delays the strength development and influences the gel formation. | [80] |
Chemical foaming | Al powder | Metakaolin | Sodium hydroxide and sodium silicate | Increasing Al content leads to an increase in porosity and a decrease in thermal conductivity. | [74] | |||
Chemical foaming | Al powder and H2O2 | Fly ash | Sodium hydroxide and sodium silicate | 70 | 24 | n.r. | H2O2 as foaming agent leads to small pores and a compressive strength of 3.7 MPa (2.0 wt. % H2O2) Al powder as foaming agent leads to larger pores and a compressive strength of 3.3 MPa (0.2 wt. % Al powder). | [81] |
Chemical foaming | H2O2 | Metakaolin and fly ash | Sodium hydroxide and sodium silicate | 40 | 24 | 65 | NaOH concentration has an effect on compressive strength and thermal conductivity. | [82] |
Chemical foaming | H2O2 | Metakaolin and fly ash | Sodium hydroxide and sodium silicate | 40 | 24 | 65 | H2O2 content affects the physical properties (porosity, mechanical resistance and thermal conductivity). | [42] |
Chemical foaming | H2O2 | Metakaolin and fly ash | Sodium hydroxide and sodium silicate | Increasing H2O2-content leads to a decrease in compressive strength and thermal conductivity, and an increase in porosity. | [73] | |||
Chemical foaming | H2O2 and different surfactants | Metakaolin | Sodium hydroxide and sodium silicate | RT + 60 | 10 + 24 | n.r. | The surfactant influences the morphology and topology of the network and therefore the mechanical properties. | [83] |
Chemical and mechanical foaming | H2O2 and SDS | Granulated blast-furnace slag and fly ash | Sodium hydroxide and sodium silicate | 60 | 24 | n.r. | Foam stabilizer enhances the pore size distribution and the pre-made foams are more stable. | [34] |
Mechanical foaming | SDS | Granulated blast-furnace slag | Sodium hydroxide and sodium silicate | 60 | 24 | n.r. | A lower Si/Al ratio leads to higher strength, and a higher Si/Al ratio leads to a lower amount of crystalline structures. | [84] |
Mechanical foaming | SDS | Granulated blast-furnace slag and fly ash | Sodium hydroxide and sodium silicate | Increasing XG concentration leads to an increase in compressive strength and a decrease in thermal conductivity | [34] | |||
Mechanical foaming | Super-plasticizer | Fly ash | Sodium hydroxide and sodium silicate | RT + 60 | 24 | n.r. | Higher compressive strength with heat curing (60 °C). | [29] |
Syntactic foams | Cenospheres | Fly ash and ground granulated blast-furnace slag | Sodium metasilicate | RT | n.r. | n.r. | Strong bonding between cenospheres and the geopolymer matrix results in a compressive strength of 17.5 MPa at a density of 978 kg/m3 and a thermal conductivity of 0.28 W/(m K). | [77] |
Syntactic foams | Fly ash cenospheres | Metakaolin | Potassium silicate | 80 | 144 | n.r. | Increasing the amount of cenospheres leads to a decrease in compressive strength, thermal conductivity and density. | [84] |
Syntactic foams | Hollow glass microspheres | Fly ash | Sodium hydroxide and sodium silicate | 60 | 24 | n.r. | Increasing the amount of hollow glass microspheres leads to a decrease in density and compressive strength. | [85] |
Syntactic foams | Hollow phenolic microspheres and hollow glass microspheres | Metakaolin | Sodium hydroxide and sodium silicate | 40 + 60 + RT | 2 + 24 + 144 | n.r. | Increasing the amount of hollow microspheres leads to a decrease in compressive strength. | [78] |
SDS = sodium dodecyl sulphate, n.r. = not reported, RT = room temperature, XG = Xanthan Gum.