Table 3.
Proton conductivity as a function of temperature and calculated activation energy (Ea).
| Copolymers | IECw(dry) (meq/g) | IECv(wet)a (meq/cm3) | Proton conductivity (mS/cm) | Eab (kJ/mol) | |||
|---|---|---|---|---|---|---|---|
| 25°C | 50°C | 60°C | 80°C | ||||
| TRP-BP 1:1-35 | 1.27 ± 0.01 | 1.36 ± 0.07 | 69 ± 1 | 72 ± 2 | 75 ± 2 | 82 ± 2 | 2.68 |
| TRP-BP 2:1-35 | 1.23 ± 0.01 | 1.35 ± 0.07 | 66 ± 2 | 72 ± 1 | 75 ± 1 | 82 ± 2 | 3.41 |
| TRP-BP 1:2-40 | 1.46 ± 0.01 | 1.22 ± 0.06 | 76 ± 6 | 83 ± 3 | 85 ± 6 | 91 ± 8 | 3.37 |
| TRP-BP 1:1-40 | 1.43 ± 0.01 | 1.33 ± 0.08 | 70 ± 6 | 92 ± 5 | 100 ± 3 | 108 ± 4 | 7.68 |
| TRP-BP 1:2-50 | 1.76 ± 0.02 | 0.73 ± 0.07 | 58 ± 1 | 83 ± 4 | 88 ± 6 | 94 ± 10 | 7.88 |
| TRP-BP 1:1-50 | 1.70 ± 0.02 | 0.63 ± 0.04 | 51 ± 3 | 72 ± 2 | 80 ± 3 | 83 ± 3 | 8.81 |
| PENT-BP 1:2-40 | 1.35 ± 0.01 | 1.55 ± 0.08 | 40 ± 4 | 61 ± 1 | 71 ± 1 | 80 ± 6 | 11.4 |
| PENT-BP 1:1-40 | 1.27 ± 0.01 | 1.49 ± 0.06 | 30 ± 3 | 49 ± 8 | 59 ± 2 | 73 ± 4 | 14.4 |
| PENT-BP 1:2-50 | 1.60 ± 0.01 | 1.29 ± 0.13 | 88 ± 6 | 111 ± 2 | 117 ± 7 | 133 ± 6 | 6.56 |
| BPSH 30 | 1.25 ± 0.01 | 1.53 ± 0.05 | 43 ± 6 | 59 ± 3 | 75 ± 5 | 78 ± 3 | 10.1 |
| BPSH 40 | 1.59 ± 0.02 | 1.54 ± 0.06 | 78 ± 3 | 109 ± 10 | 115 ± 14 | 132 ± 10 | 8.36 |
| BPSH 50 | 1.96 ± 0.02 | 1.41 ± 0.07 | 109 ± 5 | 118 ± 3 | 127 ± 4 | 139 ± 8 | 3.88 |
Calculated using Equation (5).
Calculated using Equation (7).