Figure 11.

Terpene skeletons formed by the 34 functional tomato terpene synthases. New enzymatic terpene products reported in this study are shown in bold, the corresponding terpene synthase (TPS) enzymes are showing beneath each compound with different colours: light green, dimethylallyl diphosphate (DMAPP) as substrate; dark red, geranyl diphosphate (GPP) as substrate; magenta, neryl diphosphate (NPP) as substrate; dark blue, trans‐farnesyl diphosphate (E,E‐FPP) as substrate; light blue, cis‐farnesyl diphosphate (Z,Z‐FPP) as substrate; orange, geranylgeranyl diphosphate (GGPP) as substrate; yellow, nerylneryl diphosphate (NNPP) as substrate. Enzymes characterised by transiently expressing in tobacco are indicated with asterisks, all other enzymes are characterised by in vitro enzyme assays (detailed in Supporting Information Table S6). Elemol is the thermal breakdown product of (+)‐hedycaryol; β‐elemene and δ‐elemene are the thermal rearrangements of germacrene A and germacrene C, respectively. Terpenes detected from tomato tissues are underlined.