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. 2020 Jul 31;5(31):19639–19653. doi: 10.1021/acsomega.0c02271

Table 1. Band Assignments for the Neat Microcapsulesa.

wavenumber (cm–1) intensity band assignment molecular structure material refs
1653 vw, shoulder δ(N–H) N–H melamine–formaldehyde (72)
1548 s, broad ν triazine ring melamine–formaldehyde (73)
1500 s, broad δ(C–H) C–H, in CH2, CH2–OH, CH2–O– melamine–formaldehyde (71, 74)
1470 vs asymmetric, δ(C–H) CH2 paraffin (72)
1455 s, broad δ(C–H) C–H, in CH2, CH2–OH, CH2–O– melamine–formaldehyde (71, 73, 74)
1367 w symmetric, δ(C–H), C–H, in CH2, CH2–OH, CH2–O–CH2, bridge melamine–formaldehyde (72)
1341 s, broad ν(C–N) aromatic C–N melamine–formaldehyde (73)
1156 s, broad ν(C–N) C–N/–CH2–O– melamine–formaldehyde (73)
1070 vw symmetric, ν(C–O) –CH2–O–CH2–, ether melamine–formaldehyde (73)
891 m twisting C–H in CH2 paraffin (72)
813 s δ triazine ring melamine–formaldehyde (73)
755 w δ N–H, in amines, triazine ring melamine–formaldehyde (73)
716 vs δ, in-plane rocking C–H in CH2 paraffin (72)
a

Abbreviations for band intensities. vw: very weak; w: weak; m: medium; s: strong; and vs: very strong.