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. Author manuscript; available in PMC: 2021 Aug 12.
Published in final edited form as: Chem Rev. 2020 Jul 5;120(15):7104–7151. doi: 10.1021/acs.chemrev.0c00243

Table 10.

Relative Rates of DCl-Catalyzed Hydrolysis in D2O at 60°C, and Estimated Accelerations from Participation

Substrate Rel Rate Field Effect Parameter Acceleration due to Participation
graphic file with name nihms-1606546-t0034.jpg 1 0 -
graphic file with name nihms-1606546-t0035.jpg 1.5 0 -
graphic file with name nihms-1606546-t0036.jpg 0.5 0.01 -
graphic file with name nihms-1606546-t0037.jpg 1.3 0.01 -
graphic file with name nihms-1606546-t0038.jpg 0.02 0.59 -
graphic file with name nihms-1606546-t0039.jpg 0.04 0.59 -
graphic file with name nihms-1606546-t0040.jpg 0.3 0.34 3
graphic file with name nihms-1606546-t0041.jpg 0.4 0.34 2
graphic file with name nihms-1606546-t0042.jpg 1.3 0.26 7
graphic file with name nihms-1606546-t0043.jpg 4.1 0.26 13
graphic file with name nihms-1606546-t0044.jpg 2.5 0.35 25
graphic file with name nihms-1606546-t0045.jpg 7.8 0.35 45