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. Author manuscript; available in PMC: 2021 Aug 12.
Published in final edited form as: Chem Rev. 2020 Jul 5;120(15):7104–7151. doi: 10.1021/acs.chemrev.0c00243

Table 4.

Half-lives and Product Distributions for the Consumption of Acetobromoglucose by Silver Carbonate With and Without Equimolar Amounts of Methanol

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Solvent Product with methanol t1/2 with MeOH (min) t1/2 without MeOH (min)
Glucoside (%) Orthoester (%)
Et2O 40 1 15 >1000
THF 0 50 70 70
EtOAc 10 10 10 25
CH2Cl2 30 10 15 50
acetone 5 30 10 15