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. Author manuscript; available in PMC: 2021 Aug 12.
Published in final edited form as: Chem Rev. 2020 Jul 5;120(15):7104–7151. doi: 10.1021/acs.chemrev.0c00243

Table 7.

Donor/Activator Pairs Benefitting from Anchimeric Assistance

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XR Activator
O-(Benz-1,3-oxazol-2-yl) Cu(OTf)2 and DMTST
O-5-pentenyl IDCP, but not NIS, NBS, or NIS/TfOH
S-Et MeOTf, DMTST, I2, but not IDCP
S-Ph and S-tolyl I2, no significant difference
S-(1,3-thiazolin-2-yl) I2, no significant difference