Table 1.
Simulated parameters for CW-EPR spectra obtained with the easyspin, chili method, in the presence of two species at a g tensor of [2.0087 2.006 2.0022].
| Sample | A-Tensor [MHz] (±1.0 MHz) |
τ (Correlation Time (Sec)) (±0.05 × 10−9) |
Exchange/Dipolar Interaction [MHz] (±0.1 MHz) |
% Species (±1.0%) |
|---|---|---|---|---|
| MBD1-3 | [25 25 88] | 1 × 10−10 | 5.0 | 10% |
| [25 25 92] | 1 × 10−6 | 6.0 | 90% | |
| MBD1-3 + Cu(I) | [25 25 88] | 1 × 10−10 | 5.0 | 15% |
| [25 25 92] | 1 × 10−6 | 6.0 | 85% | |
| MBD1-3 + Atox1 | [25 25 88] | 1 × 10−10 | 5.0 | 95% |
| [25 25 92] | 1 × 10−6 | 6.0 | 5% | |
| MBD1-3 + Atox1 + Cu(I) | [25 25 88] | 1 × 10−10 | 5.0 | 95% |
| [25 25 92] | 1 × 10−6 | 6.0 | 5% | |
| MBD1-3+ sl-Atox1 + Cu(I) | [25 25 88] | 1 × 10−10 | 5.0 | 30% |
| [25 25 92] | 1 × 10−6 | 6.0 | 70% | |
| MBD3-4 | [25 25 90] | 1 × 10−9 | 5.0 | 98% |
| [25 25 86] | 1 × 10−9 | 0.0 | 2% | |
| MBD3-4 + Cu(I) | [25 25 90] | 1 × 10−9 | 5.0 | 85% |
| [25 25 88] | 0.6 × 10−10 | 0.0 | 15% | |
| MBD3-4 + sl-Atox1 + Cu(I) | [25 25 90] | 1 × 10−9 | 5.0 | 85% |
| [25 25 88] | 0.6 × 10−10 | 0.0 | 15% | |
| MBD4-6 | [25 25 88] | 1 × 10−10 | 3.0 | 16% |
| [25 25 92] | 1 × 10−6 | 6.0 | 84% | |
| MBD4-6 + Cu(I) | [25 25 88] | 1 × 10−10 | 3.0 | 16% |
| [25 25 92] | 1 × 10−6 | 6.0 | 84% | |
| MBD4-6 + Atox1 | [25 25 90] | 6 × 10−9 | 0.0 | 100% |
| MBD4-6 + Atox1 + Cu(I) | [25 25 90] | 6 × 10−9 | 0.0 | 100% |
| MBD4-6 + sl-Atox1 + Cu(I) | [25 25 88] | 1 × 10−10 | 5.0 | 50% |
| [25 25 92] | 1 × 10−6 | 6.0 | 50% |