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Temperature dependence of translational (DT) and rotational (DR) diffusivity of AuNRs measured by DLS. The AuNRs are functionalized with NIPAm-PNIPAm-SH and Bn-PNIPAm-SH brushes with different molecular weights, and DT and DR diffusivity are shown in figures (a,b) and (c,d), respectively. The continuous lines are spline interpolation of the data for the eyes.
