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Temperature dependence of the normalized translational diffusivity for (a) NIPAm-PNIPAm-SH and (b) Bn-PNIPAm-SH polymer brushes onto AuNRs measured by HRNMR diffusometry. The functionalized AuNRs–PNIPAm concentration in D2O was cAuNRs = 50 mg mL–1.
