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. 2020 Aug 18;11:4145. doi: 10.1038/s41467-020-17923-w

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© The Author(s) 2020

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.

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Fig. 4 — Laser-on (−0.09 ps) and laser-om $K_{α}$ XES spectra of MbNO at different time delays between 0.26 and 1.36 ps (from blue to red) showing an intensity decrease for K_α2 over the first 1.2 ps after excitation and an intensity decrease and change in peak width for K_α1. Also, the visibility of changes in peak width (σ) smaller than the energy resolution (~0.6 eV) can be well observed. The insets zoom into the peaks of the K_α2 and K_α1 laser-on (pumped) XES spectra of MbNO at different time delays between −0.09 and 1.36 ps (from blue to red) showing an intensity decrease for K_α2 over the first 1.2 ps after excitation and an intensity decrease and change in peak width for K_α1. The changes in peak width (σ) smaller than the energy resolution (~0.6 eV) can be well observed.