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. 2020 Aug 4;13(15):3441. doi: 10.3390/ma13153441

Table A2.

Measured diffusivities for transition elements in aluminum (data calculated are indicated).

Element Group−Period Pre−Exponential Do Activation Enthalpy, Q D at 500 °C (773 K) Temp Range,
°C
Reference
- - m2s−1 kJmol−1 eVatom−1 m2s−1 - -
Ti 4−3 1.12 × 10−1 261.5 2.71 2.38 × 10−19 - [163]
9 × 10−5 223.8 2.32 6.77 × 10−20 Calc [36]
Zr 4−4 7.28+10.4−4.29 × 10−2 242 2.51 3.2 × 10−18 531−640 [164]
V 5−3 6.05 × 10−12 82.0 0.85 1.74 × 10−17 - [165]
1.6× 100 303 3.14 5.35 × 10−21 - [163]
1 × 10−4 241 2.50 5.18 × 10−21 Calc [36]
Nb 5−4 1.66 × 10−11 82.22 0.85 4.61 × 10−17 350−480 [166]
Cr 6−3 3.01 × 10−11 64.4 0.67 1.0 × 10−15 250−605 [167]
10 282 2.92 8.78 × 10−19 - [168]
6.75 × 10−1 261.5 2.71 1.44 × 10−18 - [161]
7 × 10−5 199.7 2.07 2.24 × 10−18 Calc [36]
Mo 6−4 1.4 × 10−3 250 2.59 1.79 × 10−20 - [169]
Mn 7−3 1.04 × 10−2 211 2.19 5.73 × 10−17 460−660 [170]
2.2 × 10−5 120.5 1.25 1.58 × 10−13 450−650 [32]
1.35 × 10−2 211 2.19 7.44 × 10−17 - [161]
2 × 10−5 166.9 1.73 1.05 × 10−16 Calc [36]
Fe 8−3 4.1 × 10−13 58.16 0.61 5.0 × 10−17 350−630 [171]
7.7 × 10−1 221 2.29 8.95 × 10−16 - [168]
1.35 × 10−2 190 2.00 1.95 × 10−15 - [172]
3 × 10−5 145.7 1.51 4.28 × 10−15 Calc [36]
Co 9−3 1.41 ± 1.37 × 10−2 168.8 ± 6.75 1.75 ± 0.07 5.52 × 10−14 - [173]
1.1 × 10−10 83.26 0.86 2.6 × 10−16 350−630 [171]
1.93 × 10−2 168 1.75 8.57 × 10−14 - [161,168]
1.6 × 10−6 112.9 1.17 3.75 × 10−14 Calc [36]
Ni 10−3 4.4 ± 3.l × 10−4 146 ± 5.8 1.51 ± 0.06 5.99 × 10−14 - [173]
2.9 × 10−12 65.69 0.68 1.0 × 10−16 350−630 [171]
4.1× 10−4 144.7 1.50 6.83 × 10−14 - [161]
2 × 10−4 137.0 1.42 1.1 × 10−13 Calc [36]
Cu 11−3 6.47 × 10−5 135.0 ± 1.12 1.40 ± 0.011 4.88 × 10−14 - [174]
4.37 × 10−6 120 1.25 3.39 × 10−14 - [158]
2.9 × 10−5 130 ± 6.7 1.35 ± 0.07 4.76 × 10−14 - [175]
4.44 × 10−5 113.8 1.18 9.06 × 10−13 Calc [176]
Ag 11−4 1.18 × 10−5 116.4 ± 0.59 1.21 ± 0.006 1.61 × 10−13 - [174]
Zn 12−3 2.59 × 10−5 120.7 ± 0.56 1.25 ± 0.006 1.80 × 10−13 - [174]
2.0 ± 0.8 × 10−5 120.7 ± 1.92 1.25 ± 0.02 1.39 × 10−13 - [173]
1.0 × 10−4 130 1.34 1.6 × 10−13 - [177]