Skip to main content
. Author manuscript; available in PMC: 2020 Aug 19.
Published in final edited form as: Curr Opin Chem Biol. 2017 Jan 27;37:48–55. doi: 10.1016/j.cbpa.2016.12.027

Figure 3.

Figure 3

(a) The structure of protoporphyrin-IX (PPIX), porphycene and associated complexes, (b) Benzylic oxygenation catalyzed by Mb⊂Mn-porphycene. (c) The mutations and resulting catalytic profile of selected variants of Mb⊂lr(Me)-PPIX for the reaction shown. (d) Intramolecular and intermolecular C–H insertion catalyzed by CYP119⊂lr(Me)-PPIX.