Table 2.
Evaluation of the chromatographic peak area of tabun and heptan-1-ol at m/z 70 as a linear function of their concentration (critical values of the correlation coefficient RCRIT 0.99 and QC coefficient QCCRIT 5.00).
| GC/MS compound | 7890A/5975C | Intuvo 9000/5977B | EM 640 | |||
|---|---|---|---|---|---|---|
| Tabun | Heptanol | Tabun | Heptanol | Tabun | Heptanol | |
| Retention time (min) | 13.3 | 10.4 | 10.3 | 7.8 | 12.6 | 9.8 |
| Linearity range (mg/L) | 2.5–40 | 2.5–40 | 0.5–10 | 0.5–10 | 10–50 | 10–50 |
| R | 0.9988 | 0.9994 | 0.9999 | 0.9968 | 0.9999 | 0.9996 |
| QC | 3.28 | 2.56 | 0.86 | 4.13 | 0.21 | 1.49 |
| Gradient (A × 10−6 × L/mg) | 0.71 | 1.4 | 0.13 | 0.25 | 0.015 | 0.032 |
| Intercept (A × 10−6) | 0.065 | −0.34 | −0.0030 | −0.0090 | 0.00012 | −0.015 |
| Response factor FR | 0.49 | 0.52 | 0.48 | |||
| Average value of FR | 0.50 | |||||