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. Author manuscript; available in PMC: 2020 Aug 21.
Published in final edited form as: Tetrahedron. 2019 Jun 3;75(32):4222–4227. doi: 10.1016/j.tet.2019.05.043

Table 3.

Late-Stage Deoxyfluorination of Natural Products Containing Alcohol Groupsa.

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a

Yields of isolated material. Performed with oxalate (1.0 equiv.), photocatalyst (1 mol%), Selectfluor® (1.7–2.25 equiv.), and Na2HPO4 (2.0 equiv.) Ratios of diastereomers determined by 1H NMR or 19F NMR analysis of the crude mixtures.

b

Oxalate was synthesized by an alternate method, see SI for details.