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. 2020 Aug 21;15(8):e0229477. doi: 10.1371/journal.pone.0229477

Table 7. Wavenumbers and intensity of selected bands from the experimental IR and Raman spectra of studied compounds.

Chromone Flavone 3-hydroxyflavone 3,7-Dihydroxyflavone Galangin Kaemferol Quercetin Assignment
IR R IR R IR R IR R IR R IR R IR R
3208 s 3575–3259 s 3500–3184 s 3352–3325 s 3390–3250 s νOH
3085 m* 3070 vs 3059 w 3068 m 3072 w 3072 w 3078 w 3070 m 3079 w 3075 w 3080 w νCH
1650 vs 1669 m 1646 vs 1634 vs 1607 vs 1618 vs 1610 vs 1637 vs 1658 vs 1661 s 1657 vs 1649 w 1664 s 1661 w νC = O
1616 s 1636 vw 1619 m 1618 m 1627 sh 1626 s 1632 vs 1628 vs 1619 vs 1608 vs 1612 vs 1608 vs νCC
1600 m 1615 s 1606 m 1604 s 1596 s 1599 s 1607 vs 1603 vs 1599 vs νCC
1566 m 1567 m 1569 m 1570 m 1562 s 1567 s 1572 s 1576 m 1565 s 1567 s 1564 m 1558 s 1562 s 1548 s νCC
1520 m 1521 vw 1514 m 1522 w 1511 s 1520 m 1522 s νCC
1474 sh 1496 m 1481 s 1492 w 1499 w 1496 w νCC
1462 vs 1463 w 1466 s 1470 w 1470 s 1472 w 1467 s 1450 m 1468 w 1453 w 1443 m 1462 m 1440 s νCC
1405 s 1506 w 1406 w 1416 s 1414 m 1428 m 1416 m 1399 w 1422 m 1408 m 1403 m νCC
1286 s 1310 m 1284 vs 1310 m 1319 s 1301 m 1319 s 1319 s 1320 s 1326 s βOH
1235 m 1241 m 1225 m 1235 m 1212 s 1230 w 1208 m 1219 s 121 9 w 1219 s 1215 w 1200 s 1220 w νCOC, νCC
1184 m 1189 w 1177 vs 1177 m 1175 vs 1187 w 1166 vs 1171 s 1168 vs 1177 w νC-OH
1126 s 1128 m 1129 s 1132 w 1130 s 1132 w 1133 s 1140 w 1126 m 1112 m 1119 w 1132 m 1138 w βCH
1078 w 10 86 w 1078 w 1080 w 1076 m 1074 w 1072 m 1089 w 1086 m 1088 w 1092 m 1113 m νCH
1035 m 1036 m 1044 m 1046 w 1034 m 1035 w 1032 w 1031 m νCH
1011 m 1014 m 1010 w 1000 m 999 m 993 m 1008 w 1001 s 1008 m 1002 m 1007 s 1007 w 1014 s 1014 vw νCH
969 m 966 w 959 w 963 vw 956 w 956 w 964 w 965 w 977 m 978 m 977 m 979 w νCH
906 m 907 vw 898 m 884 m 882 m 882 s 882 w
841 s 851 m 853 w 839 w 826 m 844 w 836 m 828 m 819 w 824 s γCH
775 s 774 w 769 s 774 w 776 s 777 w 772 m 767 w 795 vw 796 m 786 w
758 s 756 s 759 vs 759 m 769 m 769 vw 768 w 785 w 771 w γCH
680 m 687 m 674 w 704 s 707 w 691 s 699 w 702 m 709 w 704 m 729 w 702 m 721 w αCCC
686 w 673 m 690 s 674 w 690 sh 688 vw 687 w 688 w 681 s 661 w αCCC
648 w 657 w 656 vw 636 m 639 w 638 m 639 w 659 w γC = O
623 m 621 w 623 m 621 w 617 w 614 w 616 w 639 m 640 w γOH
576 m 578 w 579 w 585 w 580 w 584 w 604 m αCCC
525 m 534 w 528 m 513 w 510 w 513 vw 512 w 517 w 526 w 525 w 521 w 522 w 527 w 522 w αCCC
470 m 500 w 474 m 473 m 470 w 463 w 450 w ϕCC
404 m 456 w 438 w 412 w 410 w 408 w ϕCC

symbols denote: ν—stretching, β—deforming in-plane, γ—out of plane bending vibrations; α—deforming in plane of the aromatic ring; ϕ–deforming out of plane of the aromatic ring s—strong, m—medium, w—weak, v—very, sh—shoulder.