Table 7. Wavenumbers and intensity of selected bands from the experimental IR and Raman spectra of studied compounds.
Chromone | Flavone | 3-hydroxyflavone | 3,7-Dihydroxyflavone | Galangin | Kaemferol | Quercetin | Assignment | |||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
IR | R | IR | R | IR | R | IR | R | IR | R | IR | R | IR | R | |
3208 s | 3575–3259 s | 3500–3184 s | 3352–3325 s | 3390–3250 s | νOH | |||||||||
3085 m* | 3070 vs | 3059 w | 3068 m | 3072 w | 3072 w | 3078 w | 3070 m | 3079 w | 3075 w | 3080 w | νCH | |||
1650 vs | 1669 m | 1646 vs | 1634 vs | 1607 vs | 1618 vs | 1610 vs | 1637 vs | 1658 vs | 1661 s | 1657 vs | 1649 w | 1664 s | 1661 w | νC = O |
1616 s | 1636 vw | 1619 m | 1618 m | 1627 sh | 1626 s | 1632 vs | 1628 vs | 1619 vs | 1608 vs | 1612 vs | 1608 vs | νCC | ||
1600 m | 1615 s | 1606 m | 1604 s | 1596 s | 1599 s | 1607 vs | 1603 vs | 1599 vs | νCC | |||||
1566 m | 1567 m | 1569 m | 1570 m | 1562 s | 1567 s | 1572 s | 1576 m | 1565 s | 1567 s | 1564 m | 1558 s | 1562 s | 1548 s | νCC |
1520 m | 1521 vw | 1514 m | 1522 w | 1511 s | 1520 m | 1522 s | νCC | |||||||
1474 sh | 1496 m | 1481 s | 1492 w | 1499 w | 1496 w | νCC | ||||||||
1462 vs | 1463 w | 1466 s | 1470 w | 1470 s | 1472 w | 1467 s | 1450 m | 1468 w | 1453 w | 1443 m | 1462 m | 1440 s | νCC | |
1405 s | 1506 w | 1406 w | 1416 s | 1414 m | 1428 m | 1416 m | 1399 w | 1422 m | 1408 m | 1403 m | νCC | |||
1286 s | 1310 m | 1284 vs | 1310 m | 1319 s | 1301 m | 1319 s | 1319 s | 1320 s | 1326 s | βOH | ||||
1235 m | 1241 m | 1225 m | 1235 m | 1212 s | 1230 w | 1208 m | 1219 s | 121 9 w | 1219 s | 1215 w | 1200 s | 1220 w | νCOC, νCC | |
1184 m | 1189 w | 1177 vs | 1177 m | 1175 vs | 1187 w | 1166 vs | 1171 s | 1168 vs | 1177 w | νC-OH | ||||
1126 s | 1128 m | 1129 s | 1132 w | 1130 s | 1132 w | 1133 s | 1140 w | 1126 m | 1112 m | 1119 w | 1132 m | 1138 w | βCH | |
1078 w | 10 86 w | 1078 w | 1080 w | 1076 m | 1074 w | 1072 m | 1089 w | 1086 m | 1088 w | 1092 m | 1113 m | νCH | ||
1035 m | 1036 m | 1044 m | 1046 w | 1034 m | 1035 w | 1032 w | 1031 m | νCH | ||||||
1011 m | 1014 m | 1010 w | 1000 m | 999 m | 993 m | 1008 w | 1001 s | 1008 m | 1002 m | 1007 s | 1007 w | 1014 s | 1014 vw | νCH |
969 m | 966 w | 959 w | 963 vw | 956 w | 956 w | 964 w | 965 w | 977 m | 978 m | 977 m | 979 w | νCH | ||
906 m | 907 vw | 898 m | 884 m | 882 m | 882 s | 882 w | ||||||||
841 s | 851 m | 853 w | 839 w | 826 m | 844 w | 836 m | 828 m | 819 w | 824 s | γCH | ||||
775 s | 774 w | 769 s | 774 w | 776 s | 777 w | 772 m | 767 w | 795 vw | 796 m | 786 w | ||||
758 s | 756 s | 759 vs | 759 m | 769 m | 769 vw | 768 w | 785 w | 771 w | γCH | |||||
680 m | 687 m | 674 w | 704 s | 707 w | 691 s | 699 w | 702 m | 709 w | 704 m | 729 w | 702 m | 721 w | αCCC | |
686 w | 673 m | 690 s | 674 w | 690 sh | 688 vw | 687 w | 688 w | 681 s | 661 w | αCCC | ||||
648 w | 657 w | 656 vw | 636 m | 639 w | 638 m | 639 w | 659 w | γC = O | ||||||
623 m | 621 w | 623 m | 621 w | 617 w | 614 w | 616 w | 639 m | 640 w | γOH | |||||
576 m | 578 w | 579 w | 585 w | 580 w | 584 w | 604 m | αCCC | |||||||
525 m | 534 w | 528 m | 513 w | 510 w | 513 vw | 512 w | 517 w | 526 w | 525 w | 521 w | 522 w | 527 w | 522 w | αCCC |
470 m | 500 w | 474 m | 473 m | 470 w | 463 w | 450 w | ϕCC | |||||||
404 m | 456 w | 438 w | 412 w | 410 w | 408 w | ϕCC |
symbols denote: ν—stretching, β—deforming in-plane, γ—out of plane bending vibrations; α—deforming in plane of the aromatic ring; ϕ–deforming out of plane of the aromatic ring s—strong, m—medium, w—weak, v—very, sh—shoulder.