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. Author manuscript; available in PMC: 2020 Aug 25.
Published in final edited form as: J Am Chem Soc. 2020 Aug 6;142(33):14240–14248. doi: 10.1021/jacs.0c05590

Scheme 2. Evidence for Reversible Fe–C Bond Homolysisa.

Scheme 2.

a(A) Proposed mechanism for the conversion of [5]+ to [7]+. (B) Reaction of [2]+ with pyridine in the presence of an excess of [8]+ decreases the rate of bibenzyl formation.